Molecular Fullerides

The closed shell structures of certain all-carbon fragments originally observed in mass spectroscopy experiments leads to the enhanced stability of these species, known as fullerenes, which have excited sufficient interest amongst chemists and physicists over the last decade to warrant the award of the 1996 Nobel Prize for Chemistry to their discoverers. ¶ Studies of the stability, symmetry, and consequent remarkable properties of fullerenes began in earnest in 1991 with the development of a technique enabling the production and purification of macroscopic quantities of material. The best known and most widely studied fullerene is the truncated icosahedral C60 molecule, which forms the basis of the present work

Tomography of atomic number and density of materials using dual-energy imaging and the Alvarez and Macovski attenuation model

Dual-energy computed tomography and the Alvarez and Macovski [Phys. Med. Biol. 21, 733 (1976)] transmitted intensity (AMTI) model were used in this study to estimate the maps of density (ρ) and atomic number (Z) of mineralogical samples. In this method, the attenuation coefficients are represented [Alvarez and Macovski, Phys. Med. Biol. 21, 733 (1976)] in the form of the two most important interactions of X-rays with atoms that is, photoelectric absorption (PE) and Compton scattering (CS). This enables material discrimination as PE and CS are, respectively, dependent on the atomic number (Z) and density (ρ) of materials [Alvarez and Macovski, Phys. Med. Biol. 21, 733 (1976)]. Dual-energy imaging is able to identify sample materials even if the materials have similar attenuation coefficients at single-energy spectrum. We use the full model rather than applying one of several applied simplified forms [Alvarez and Macovski, Phys. Med. Biol. 21, 733 (1976); Siddiqui et al., SPE Annual Technical Conference and Exhibition (Society of Petroleum Engineers, 2004); Derzhi, U.S. patent application 13/527,660 (2012); Heismann et al., J. Appl. Phys. 94, 2073–2079 (2003); Park and Kim, J. Korean Phys. Soc. 59, 2709 (2011); Abudurexiti et al., Radiol. Phys. Technol. 3, 127–135 (2010); and Kaewkhao et al., J. Quant. Spectrosc. Radiat. Transfer 109, 1260–1265 (2008)]. This paper describes the tomographic reconstruction of ρ and Z maps of mineralogical samples using the AMTI model. The full model requires precise knowledge of the X-ray energy spectra and calibration of PE and CS constants and exponents of atomic number and energy that were estimated based on fits to simulations and calibration measurements. The estimated ρ and Z images of the samples used in this paper yield average relative errors of 2.62% and 1.19% and maximum relative errors of 2.64% and 7.85%, respectively. Furthermore, we demonstrate that the method accounts for the beam hardening effect in density (ρ) and atomic number (Z) reconstructions to a significant extent.S.J.L., G.R.M., and A.M.K. acknowledge funding through the DigiCore consortium and the support of a linkage grant (LP150101040) from the Australian Research Council and FEI Company

Radio tomography and borehole radar delineation of the McConnell nickel sulfide deposit, Sudbury, Ontario, Canada

In an effort to reduce costs and increase revenues at mines, there is a strong incentive to develop high-resolution techniques both for near-mine exploration and for delineation of known orebodies To investigate the potential of high-frequency EM techniques for exploration and delineation of massive sulfide orebodies, radio frequency electromagnetic (RFEM) and ground-penetrating radar (GPR) surveys were conducted in boreholes through the McConnell massive nickel-copper sulfide body near Sudbury, Ontario, from 1993-1996. Crosshole RFEM data were acquired with a JW-4 electric dipole system between two boreholes on section 2720W. Ten frequencies between 0.5 and 5.0 MHz were recorded. Radio signals propagated through the Sudbury Breccia over ranges of at least 150 m at all frequencies. The resulting radio absorption tomogram clearly imaged the McConnell deposit over 110 m downdip. Signal was extinguished when either antenna entered the sulfide body. However, the expected radio shadow did not eventuate when transmitter and receiver were on opposite sides of the deposit. Two-dimensional modeling suggested that diffraction around the edges of the sulfide body could not account for the observed held amplitudes. It was concluded at the time that the sulfide body is discontinuous; according to modeling, a gap as small as 5 m could have explained the observations. Subsequent investigations by INCO established that pick-up in the metal-cored downhole cables was actually responsible for the elevated signal levels. Both single-hole reflection profiles and crosshole measurements were acquired using RAMAC borehole radar systems, operating at 60 MHz. Detection of radar reflections from the sulfide contact was problematic. One coherent reflection was observed from the hanging-wall contact in single-hole reflection mode. This reflection could be traced about 25 m uphole from the contact. In addition to unfavorable survey geometry, factors which may have suppressed reflections included host rock heterogeneity, disseminated sulfides, and contact irregularity. Velocity and absorption tomograms were generated in the Sudbury Breccia host rock from the crosshole radar. Radar velocity was variable, averaging 125 m/mus, while absorption was typically 0.8 dB/m at 60 MHz. Kirchhoff-style 2-D migration of later arrivals in the crosshole radargrams defined reflective zones that roughly parallel the inferred edge of the sulfide body. The McConnell high-frequency EM surveys established that radio tomography and simple radio shadowing are potentially valuable for near- and in-mine exploration and orebody delineation in the Sudbury Breccia. The effectiveness of borehole radar in this particular environment is less certain

Conductivity tomography at two frequencies

We present a new approach for crosshole radio tomography. Conductivity images of the investigated area are reconstructed from the ratio of the electric field intensities measured at two similar frequencies. The method largely avoids assumptions about the radiation pattern and in-situ intensity of the transmitting antenna, which introduce errors in conventional single-frequency crosshole electromagnetic-absorption tomography. Application of the method to field data achieved an improvement in resolution of anomalies over traditional single-frequency absorption tomography. The dual-frequency method is not a universal approach; it is suitable for moderately conductive media (>0.01 S/m) over the approximate frequency range 1-100 MHz

Are they ‘worth their weight in gold’? Sport for older adults: benefits and barriers of their participation for sporting organisations

The ageing global population has led to an increased focus on health for older adults. However, older adults have not been a specific priority for some sporting organisations (SOs). Thus, there is an emerging opportunity for this age group to be considered within international sport policy. The aim of this study was to understand the benefits and barriers that SOs encounter when engaging older adults. Eight focus group interviews (n = 49) were held with representatives of Australian national sporting organisations (NSOs), and older adults who were either sport club or non-sport club members. The socioecological model domains, interpersonal, organisational and policy, were used as a framework for thematic analysis, and organisational capacity building concepts were utilised to explain the findings. Common perceived benefits included interpersonal benefits (intergenerational opportunities and role models) and organisational benefits (volunteering, financial contributions and maximised facility usage) for engaging older adults. Common perceived barriers included interpersonal barriers (competing priorities and perceived societal expectations), organisational barriers (lack of appropriate playing opportunities, lack of facility access and lack of club capacity) and policy barriers (strategic organisational focus on children and elite sport and risk management). Whilst participation in sport is not common for older adults, their involvement can be invaluable for sport clubs. It is not anticipated that any policy focus on older adults will significantly increase active participation for this age group. However, any increase in older adults’ sport participation either through actively playing, supporting family and friends and/or volunteering will contribute to the positive health of individuals, sport clubs and the community.Peer reviewedFinal Accepted Versio

Professional youth football academy injury data: collection procedures, perceived value, and use

Purpose: There is a paucity of descriptive injury data relevant to professional academy football, with little to no evidence reporting how sports science/medicine staff within academies collect and use injury data. Materials and methods: An online survey relating to the perceptions surrounding injury data collection, its value and use was developed. Forty-seven applied practitioners working for different professional football academies completed the survey. Results: Injury data collection procedures conducted by appropriately trained medical staff are widespread among football academies. Injury data collection within academies was deemed worthwhile and important by 79% of practitioners. Similarly, 79% strongly agreed/agreed that using injury data for academic research is worthwhile. The engagement with and use of injury data by coaching staff appears to be relatively poor, with only 49% of practitioners stating coaches formally review data. Conclusions: Injury data are widely collected within academies and practitioners consider this information valuable. However, improving engagement with coaches and using the data for academic research could further improve applied practice. Practical implications: Applied practitioners should consider sharing injury data with both researchers and coaches. In doing so evidence-guided injury prevention interventions may be developed and subsequently applied in the field

Open science in archaeology

No abstract available